Organic light emitting device

ABSTRACT

The present disclosure relates to an organic light emitting device that includes a substrate; and an organic light emitting diode positioned on the substrate and including a first electrode; a second electrode facing the first electrode; and a first emitting material layer including a first host of an anthracene derivative and a first dopant of a boron derivative and positioned between the first and second electrodes, wherein an anthracene core of the first host is deuterated.

CROSS-REFERENCE TO RELATED APPLICATIONS

The present application claims the benefit of Korean Patent Application No. 10-2020-0065152 filed in the Republic of Korea on May 29, 2020, and Korean Patent Application No. 10-2021-0063689 filed in the Republic of Korea on May 17, 2021, all of which are hereby incorporated by reference in their entirety.

TECHNICAL FIELD

The present disclosure relates to an organic light emitting device, and more specifically, to an organic light emitting diode (OLED) having enhanced emitting efficiency and lifespan and an organic light emitting device including the same.

DISCUSSION OF THE RELATED ART

As requests for a flat panel display device having a small occupied area have been increased, an organic light emitting display device including an OLED has been the subject of recent research and development.

The OLED emits light by injecting electrons from a cathode as an electron injection electrode and holes from an anode as a hole injection electrode into an emitting material layer (EML), combining the electrons with the holes, generating an exciton, and transforming the exciton from an excited state to a ground state. A flexible substrate, for example, a plastic substrate, can be used as a base substrate where elements are formed. In addition, the organic light emitting display device can be operated at a voltage (e.g., 10\T or below) lower than a voltage required to operate other display devices. Moreover, the organic light emitting display device has advantages in the power consumption and the color sense.

The OLED includes a first electrode as an anode over a substrate, a second electrode, which is spaced apart from and faces the first electrode, and an organic emitting layer therebetween.

For example, the organic light emitting display device may include a red pixel region, a green pixel region and a blue pixel region, and the OLED may be formed in each of the red, green and blue pixel regions.

However, the OLED in the blue pixel does not provide sufficient emitting efficiency and lifespan such that the organic light emitting display device has a limitation in the emitting efficiency and the lifespan.

SUMMARY

Accordingly, embodiments of present disclosure are directed to an OLED and an organic light emitting device including the OLED that substantially obviate one or more of the problems associated with the limitations and disadvantages of the related art.

Additional features and aspects will be set forth in the description that follows, and in part will be apparent from the description, or may be learned by practice of the inventive concepts provided herein. Other features and aspects of the inventive concepts may be realized and attained by the structure particularly pointed out in the written description, or derivable therefrom, and the claims hereof as well as in the appended drawings.

To achieve these and other advantages in accordance with the purpose of the embodiments of the present disclosure, as embodied and broadly described herein, an organic light emitting device comprises a substrate; and an organic light emitting diode positioned on the substrate and including a first electrode; a second electrode facing the first electrode; and a first emitting material layer including a first host of an anthracene derivative and a first dopant of a boron derivative and positioned between the first and second electrodes, wherein an anthracene core of the first host is deuterated, and the first dopant is represented by:

each of R₁₁ to R₁₄, each of R₂₁ to R₂₄, each of R₃₁ to R₃₅ and each of R₁₁ to R₄₅ is selected from the group of hydrogen, deuterium (D), C1 to C10 alkyl, C6 to C30 aryl, C6 to C30 arylamino group and C5 to C30 heteroaryl, and wherein R₅₁ is selected from the group consisting of C12 to C30 arylamino group unsubstituted or substituted with at least one of deuterium and C1 to C10 alkyl and non-substituted or deuterated C5 to C30 heteroaryl.

It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to further explain the present disclosure as claimed.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are included to provide a further understanding of the present disclosure and are incorporated in and constitute a part of this specification, illustrate embodiments of the present disclosure and together with the description serve to explain principles of the present disclosure.

FIG. 1 is a schematic circuit diagram illustrating an organic light emitting display device of the present disclosure.

FIG. 2 is a schematic cross-sectional view illustrating an organic light emitting display device according to a first embodiment of the present disclosure.

FIG. 3 is a schematic cross-sectional view illustrating an OLED having a single emitting part for the organic light emitting display device according to the first embodiment of the present disclosure.

FIG. 4 is a schematic cross-sectional view illustrating an OLED having a tandem structure of two emitting parts according to the first embodiment of the present disclosure.

FIG. 5 is a schematic cross-sectional view illustrating an organic light emitting display device according to a second embodiment of the present disclosure.

FIG. 6 is a schematic cross-sectional view illustrating an OLED having a tandem structure of two emitting parts according to the second embodiment of the present disclosure.

FIG. 7 is a schematic cross-sectional view illustrating an OLED having a tandem structure of three emitting parts according to the second embodiment of the present disclosure.

FIG. 8 is a schematic cross-sectional view illustrating an organic light emitting display device according to a third embodiment of the present disclosure.

DETAILED DESCRIPTION

Reference will now be made in detail to some of the examples and preferred embodiments, which are illustrated in the accompanying drawings.

FIG. 1 is a schematic circuit diagram illustrating an organic light emitting display device of the present disclosure.

As illustrated in FIG. 1, a gate line GL and a data line DL, which cross each other to define a pixel (pixel region) P, and a power line PL are formed in an organic light emitting display device. A switching thin film transistor (TFT) Ts, a driving TFT Td, a storage capacitor Cst and an OLED D are formed in the pixel region P. The pixel region P may include a red pixel, a green pixel and a blue pixel.

The switching thin film transistor Ts is connected to the gate line GL and the data line DL, and the driving thin film transistor Td and the storage capacitor Cst are connected between the switching thin film transistor Ts and the power line PL. The OLED D is connected to the driving thin film transistor Td. When the switching thin film transistor Ts is turned on by the gate signal applied through the gate line GL, the data signal applied through the data line DL is applied to a gate electrode of the driving thin film transistor Td and one electrode of the storage capacitor Cst through the switching thin film transistor Ts.

The driving thin film transistor Td is turned on by the data signal applied into the gate electrode so that a current proportional to the data signal is supplied from the power line PL to the OLED D through the driving thin film transistor Td. The OLED D emits light having a luminance proportional to the current flowing through the driving thin film transistor Td. In this case, the storage capacitor Cst is charge with a voltage proportional to the data signal so that the voltage of the gate electrode in the driving thin film transistor Td is kept constant during one frame. Therefore, the organic light emitting display device can display a desired image.

FIG. 2 is a schematic cross-sectional view illustrating an organic light emitting display device according to a first embodiment of the present disclosure.

As illustrated in FIG. 2, the organic light emitting display device 100 includes a substrate 110, a TFT Tr and an OLED D connected to the TFT Tr. For example, the organic light emitting display device 100 may include a red pixel, a green pixel and a blue pixel, and the OLED D may be formed in each of the red, green and blue pixels. Namely, the OLEDs D emitting red light, green light and blue light may be provided in the red, green and blue pixels, respectively.

The substrate 110 may be a glass substrate or a plastic substrate. For example, the substrate 110 may be a polyimide substrate.

A buffer layer 120 is formed on the substrate, and the TFT Tr is formed on the buffer layer 120. The buffer layer 120 may be omitted.

A semiconductor layer 122 is formed on the buffer layer 120. The semiconductor layer 122 may include an oxide semiconductor material or polycrystalline silicon.

When the semiconductor layer 122 includes the oxide semiconductor material, a light-shielding pattern (not shown) may be formed under the semiconductor layer 122. The light to the semiconductor layer 122 is shielded or blocked by the light-shielding pattern such that thermal degradation of the semiconductor layer 122 can be prevented. On the other hand, when the semiconductor layer 122 includes polycrystalline silicon, impurities may be doped into both sides of the semiconductor layer 122.

A gate insulating layer 124 is formed on the semiconductor layer 122. The gate insulating layer 124 may be formed of an inorganic insulating material such as silicon oxide or silicon nitride.

A gate electrode 130, which is formed of a conductive material, e.g., metal, is formed on the gate insulating layer 124 to correspond to a center of the semiconductor layer 122.

In FIG. 2, the gate insulating layer 124 is formed on an entire surface of the substrate 110. Alternatively, the gate insulating layer 124 may be patterned to have the same shape as the gate electrode 130.

An interlayer insulating layer 132, which is formed of an insulating material, is formed on the gate electrode 130. The interlayer insulating layer 132 may be formed of an inorganic insulating material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl.

The interlayer insulating layer 132 includes first and second contact holes 134 and 136 exposing both sides of the semiconductor layer 122. The first and second contact holes 134 and 136 are positioned at both sides of the gate electrode 130 to be spaced apart from the gate electrode 130.

The first and second contact holes 134 and 136 are formed through the gate insulating layer 124. Alternatively, when the gate insulating layer 124 is patterned to have the same shape as the gate electrode 130, the first and second contact holes 134 and 136 is formed only through the interlayer insulating layer 132.

A source electrode 140 and a drain electrode 142, which are formed of a conductive material, e.g., metal, are formed on the interlayer insulating layer 132.

The source electrode 140 and the drain electrode 142 are spaced apart from each other with respect to the gate electrode 130 and respectively contact both sides of the semiconductor layer 122 through the first and second contact holes 134 and 136.

The semiconductor layer 122, the gate electrode 130, the source electrode 140 and the drain electrode 142 constitute the TFT Tr. The TFT Tr serves as a driving element. Namely, the TFT Tr may correspond to the driving TFT Td (of FIG. 1).

In the TFT Tr, the gate electrode 130, the source electrode 140, and the drain electrode 142 are positioned over the semiconductor layer 122. Namely, the TFT Tr has a coplanar structure.

Alternatively, in the TFT Tr, the gate electrode may be positioned under the semiconductor layer, and the source and drain electrodes may be positioned over the semiconductor layer such that the TFT Tr may have an inverted staggered structure. In this instance, the semiconductor layer may include amorphous silicon.

Although not shown, the gate line and the data line cross each other to define the pixel, and the switching TFT is formed to be connected to the gate and data lines. The switching TFT is connected to the TFT Tr as the driving element.

In addition, the power line, which may be formed to be parallel to and spaced apart from one of the gate and data lines, and the storage capacitor for maintaining the voltage of the gate electrode of the TFT Tr in one frame may be further formed.

A passivation layer 150, which includes a drain contact hole 152 exposing the drain electrode 142 of the TFT Tr, is formed to cover the TFT Tr.

A first electrode 160, which is connected to the drain electrode 142 of the TFT Tr through the drain contact hole 152, is separately formed in each pixel. The first electrode 160 may be an anode and may be formed of a conductive material having a relatively high work function. For example, the first electrode 160 may be formed of a transparent conductive material such as indium-tin-oxide (ITO) or indium-zinc-oxide (IZO).

When the OLED device 100 is operated in a top-emission type, a reflection electrode or a reflection layer may be formed under the first electrode 160. For example, the reflection electrode or the reflection layer may be formed of aluminum-palladium-copper (APC) alloy.

A bank layer 166 is formed on the passivation layer 150 to cover an edge of the first electrode 160. Namely, the bank layer 166 is positioned at a boundary of the pixel and exposes a center of the first electrode 160 in the pixel.

An organic emitting layer 162 is formed on the first electrode 160. The organic emitting layer 162 may have a single-layered structure of an emitting material layer including an emitting material. To increase an emitting efficiency of the OLED D and/or the organic light emitting display device 100, the organic emitting layer 162 may have a multi-layered structure.

The organic emitting layer 162 is separated in each of the red, green and blue pixels. As illustrated below, the organic emitting layer 162 in the blue pixel includes a host of an anthracene derivative (anthracene compound), a core of which is deuterated, and a dopant of a boron derivative such that the emitting efficiency and the lifespan of the OLED D in the blue pixel are improved.

A second electrode 164 is formed over the substrate 110 where the organic emitting layer 162 is formed. The second electrode 164 covers an entire surface of the display area and may be formed of a conductive material having a relatively low work function to serve as a cathode. For example, the second electrode 164 may be formed of aluminum (Al), magnesium (Mg) or Al—Mg alloy.

The first electrode 160, the organic emitting layer 162 and the second electrode 164 constitute the OLED D.

An encapsulation film 170 is formed on the second electrode 164 to prevent penetration of moisture into the OLED D. The encapsulation film 170 includes a first inorganic insulating layer 172, an organic insulating layer 174 and a second inorganic insulating layer 176 sequentially stacked, but it is not limited thereto. The encapsulation film 170 may be omitted.

A polarization plate (not shown) for reducing an ambient light reflection may be disposed over the top-emission type OLED D. For example, the polarization plate may be a circular polarization plate.

In addition, a cover window (not shown) may be attached to the encapsulation film 170 or the polarization plate. In this instance, the substrate 110 and the cover window have a flexible property such that a flexible display device may be provided.

FIG. 3 is a schematic cross-sectional view illustrating an OLED having a single emitting part for the organic light emitting display device according to the first embodiment of the present disclosure.

As illustrated in FIG. 3, the OLED D includes the first and second electrodes 160 and 164, which face each other, and the organic emitting layer 162 therebetween. The organic emitting layer 162 includes an emitting material layer (EML) 240 between the first and second electrodes 160 and 164.

The first electrode 160 may be formed of a conductive material having a relatively high work function to serve as an anode. The second electrode 164 may be formed of a conductive material having a relatively low work function to serve as a cathode.

The organic emitting layer 162 may further include an electron blocking layer (EBL) 230 between the first electrode 160 and the EML 240 and a hole blocking layer (HBL) 250 between the EML 240 and the second electrode 164.

In addition, the organic emitting layer 162 may further include a hole transporting layer (HTL) 220 between the first electrode 160 and the EBL 230.

Moreover, the organic emitting layer 162 may further include a hole injection layer (HIL) 210 between the first electrode 160 and the HTL 220 and an electron injection layer (EIL) 260 between the second electrode 164 and the HBL 250.

In the OLED D of the present disclosure, the HBL 250 may include a hole blocking material of a pyridine derivative. The hole blocking material has an electron transporting property such that an electron transporting layer may be omitted. The HBL 250 directly contacts the EIL 260. Alternatively, the HBL may directly contact the second electrode without the EIL 260. However, an electron transporting layer may be formed between the HBL 250 and the EIL 260.

The organic emitting layer 162, e.g., the EML 240, includes the host 242 of an anthracene derivative and the dopant 244 of a boron derivative and provides blue emission. In this instance, the core of the anthracene derivative is deuterated. In addition, a part or all of hydrogens in the boron derivative may be deuterated.

Namely, in the EML 240, the anthracene core of the host 242 is deuterated. The dopant 244 may not be deuterated or may be partially or entirely deuterated.

The host 242 of the deuterated anthracene derivative may be represented by Formula 1:

In Formula 1, each of R₁ and R₂ may be independently C₆˜C₃₀ aryl group or C₅˜C₃₀ heteroaryl group, and R₁ and R₂ may be same or different. Each of L₁ and L₂ may be independently C₆˜C₃₀ arylene group, and L₁ and L₂ may be same or different. In addition, x is an integer of 1 to 8, and each of y1 and y2 is an integer of 0 or 1.

Namely, the anthracene moiety as a core of the host 242 is substituted by deuterium (D), and the substituent except the anthracene moiety is not deuterated.

For example, R₁ and R₂ may be selected from the group consisting of phenyl, naphthyl, fluorenyl, pyridyl, quinolinyl, dibenzofuranyl, dibenzothiophenyl, phenanthrenyl, carbazolyl and carbolinyl, and L₁ and L₂ may be selected from the group consisting of phenylene and naphthylene. In addition, x may be 8.

In an exemplary embodiment, the host 242 may be a compound being one of the followings in Formula 2:

The dopant 244 of the boron derivative may be represented by Formula 3:

In Formula 3, each of R₁₁ to R₁₄, each of R₂₁ to R₂₄, each of R₃₁ to R₃₅ and each of R₄₁ to R₄₅ may be selected from the group of hydrogen, deuterium (D), C1 to C10 alkyl, C6 to C30 aryl, C6 to C30 arylamino group and C5 to C30 heteroaryl, and each of R₁₁ to R₁₄, each of R₂₁ to R₂₄, each of R₃₁ to R₃₅ and each of R₄₁ to R₄₅ may be same or different. R₅₁ may be selected from the group consisting of C12 to C30 arylamino group unsubstituted or substituted with at least one of deuterium and C1 to C10 alkyl and non-substituted or deuterated C5 to C30 heteroaryl.

In the boron derivative as the dopant 244, the benzene ring, which is combined to boron atom and two nitrogen atoms, is substituted by one of C12 to C30 arylamino group unsubstituted or substituted with at least one of deuterium and C1 to C10 alkyl and non-substituted or deuterated C5 to C30 heteroaryl such that the emitting property of the OLED D including the dopant 244 is improved.

For example, the C1 to C10 alkyl may be one of methyl, ethyl, propyl, butyl and pentyl (amyl). The aryl may be one of phenyl and naphthyl and may be substituted by deuterium or C1 to C10 alkyl. The C12 to C30 arylamino group may be one of diphenylamino group, phenyl-biphenyl amino group, phenyl-naphthylamino group and dinaphthylamino group, and the C5 to C30 heteroaryl may be one of pyridyl, quinolinyl, carbazolyl, dibenzofuranyl and dibenzothiophenyl. The arylamino group, the aryl, the alkyl and the heteroaryl may be deuterated.

In more detail, each of R₁₁ to R₁₄, each of R₂₁ to R₂₄, each of R₃₁ to R₃₅ and each of R₄₁ to R₄₅ may be selected from the group consisting of hydrogen, deuterium, methyl, ethyl, propyl, butyl and pentyl (amyl), and R₅₁ may be selected from the group consisting of non-substituted or deuterated diphenylamino group, non-substituted or deuterated phenyl-biphenyl amino group, non-substituted or deuterated phenyl-naphthylamino group, non-substituted or deuterated dinaphthylamino group and non-substituted or deuterated carbazolyl.

In one embodiment, one of R₁₁ to R₁₄, one of R₂₁ to R₂₄, one of R₃₁ to R₃₅ and one of R₄₁ to R₄₅ may be tert-butyl or tert-pentyl (tert-amyl), and the rest of R₁₁ to R₁₄, the rest of R₂₁ to R₂₄, the rest of R₃₁ to R₃₅ and the rest of R₄₁ to R₄₅ may be hydrogen or deuterium, and R₅₁ may be deuterated diphenylamino group. The OLED D includes the compound as a dopant, the emitting efficiency and the color purity of the OLED D are improved.

The dopant 244 of Formula 3 may be a compound being one of the followings in Formula 4:

In the OLED D of the present disclosure, the host 242 may have a weight % of about 70 to 99.9, and the dopant 244 may have a weight % of about 0.1 to 30. To provide sufficient emitting efficiency and lifespan of the OLED D and the organic light emitting display device, the dopant 244 may have a weight % of about 0.1 to 10, preferably about 1 to 5.

As mentioned above, in the OLED D of the present disclosure, since the EML 240 includes the host 242 of the anthracene derivative, the core of which is deuterated, and the dopant 244 of the boron derivative, the OLED D and the organic light emitting display device have advantages in the emitting efficiency and the lifespan.

SYNTHESIS OF THE HOST 1. Synthesis of Compound Host1 (1) Intermediate H-1

Anhydrous cupric bromide (45 g, 0.202 mol) was added into anthracene-D10 (18.8 g, 0.10 mol) CCl₄ solution. The mixture was heated and stirred under a nitrogen atmosphere for 12 hrs. After completion of reaction, white CuBr(I) compound was filtered off, and the residual liquid was refined by using 35 nm Alumina column. Under vacuum condition, the solvent was removed from the reaction solution, which is refined, by using column to obtain the mixture including the intermediate H-1 (9-bromoanthracene-D9).

The mixture includes the intermediate H-1, the starting material (anthracene-D10) and dibromo-byproduct. The mixture without additional refinement was used as the starting material in the reaction Formula 1-2.

(2) Intermediate H-2

The intermediate H-1 (2.66 g, 0.01 mol) and naphtalene-1-boronic acid (1.72 g, 0.01 mol) was added into the rounded-bottom flask, and toluene (30 ml) was further added to form a mixture solution. Under a nitrogen atmosphere, the mixture solution was stirred and Na₂CO₃ aqueous solution, which is formed by dissolving Na₂CO₃ (2.12 g) into distilled water (10 ml), was added. Pd(PPh₃)₄ (0.25 g, 0.025 mmol) as catalyst was further added and stirred. After completion of reaction, the reaction solution was added into methanol solution to precipitate a product, and the precipitated product was filtered. In the reduce-pressure filter, the precipitated product was washed sequentially using water, hydrogen chloride aqueous solution (10% concentration), water and methanol. The precipitated product was refined to obtain the intermediate H-2 of white powder (2.6 g).

(3) Intermediate H-3

After dissolving the intermediate H-2 (2.8 g, 8.75 mmol) into dichloromethane (50 mL), Br₂ (1.4 g, 8.75 mmol) was added and stirred under the room temperature (RT). After completion of reaction, 2M Na₂S₂O₃ aqueous solution (10 mL) was added into the reactant and stirred. The organic layer was separated and washed using Na₂S₂O₃ aqueous solution (10% concentration, 10 mL) and distilled water. The organic layer was separated again, and water in the organic layer was removed by using MgSO₄. After the organic layer was concentrated, excessive methanol was added to obtain a product. The product was filtered to obtain the intermediate H-3 (3.3 g).

(4) Host1

The intermediate H-3 (1.96 g, 0.05 mol) and naphtalene-2-boronic acid (1.02 g, 0.06 mol) were added and dissolved into toluene (30 ml). The mixture solution was stirred under a nitrogen atmosphere. Na₂CO₃ aqueous solution (1 ml), which is formed by dissolving Na₂CO₃ (1.90 g) into distilled water (8 ml), was added into the mixture solution. Pd(PPh₃)₄ (0.125 g, 0.0125 mmol) was further added. The mixture was heated and stirred under a nitrogen atmosphere. After completion of reaction, the organic layer was separated, and methanol was added into the organic layer to precipitate a white solid mixture. The white solid mixture was refined by silica-gel column chromatography using the eluent of chloroform and hexane (volume ratio=1:3) to obtain the compound Host1 (2.30 g).

2. Synthesis of Compound Host2

The intermediate H-3 (1.96 g, 0.05 mol) and 4-(naphtalene-2-yl)phenylboronic acid (1.49 g, 0.06 mol) were added and dissolved into toluene (30 ml). The mixture solution was stirred under a nitrogen atmosphere. Na₂CO₃ aqueous solution (1 ml), which is formed by dissolving Na₂CO₃ (1.90 g) into distilled water (8 ml), was added into the mixture solution. Pd(PPh₃)₄ (0.125 g, 0.0125 mmol) was further added. The mixture was heated and stirred under a nitrogen atmosphere. After completion of reaction, the organic layer was separated, and methanol was added into the organic layer to precipitate a white solid mixture. The white solid mixture was refined by silica-gel column chromatography using the eluent of chloroform and hexane (volume ratio=1:3) to obtain the compound Host2 (2.30 g).

3. Synthesis of Compound Host3 (1) Intermediate H-4

The intermediate H-1 (2.66 g, 0.01 mol) and phenylboronic acid (1.22 g, 0.01 mol) was added into the rounded-bottom flask, and toluene (30 ml) was further added to form a mixture solution. Under a nitrogen atmosphere, the mixture solution was stirred and Na₂CO₃ aqueous solution, which is formed by dissolving Na₂CO₃ (2.12 g) into distilled water (10 ml), was added. Pd(PPh₃)₄ (0.25 g, 0.025 mmol) as catalyst was further added and stirred. After completion of reaction, the reaction solution was added into methanol solution to precipitate a product, and the precipitated product was filtered. In the reduce-pressure filter, the precipitated product was washed sequentially using water, hydrogen chloride aqueous solution (10% concentration), water and methanol. The precipitated product was refined to obtain the intermediate H-4 of white powder (2.4 g).

(2) Intermediate H-5

After dissolving the intermediate H-4 (2.3 g, 8.75 mmol) into dichloromethane (50 mL), Br₂ (1.4 g, 8.75 mmol) was added and stirred under the room temperature (RT). After completion of reaction, 2M Na₂S₂O₃ aqueous solution (10 mL) was added into the reactant and stirred. The organic layer was separated and washed using Na₂S₂O₃ aqueous solution (10% concentration, 10 mL) and distilled water. The organic layer was separated again, and water in the organic layer was removed by using MgSO₄. After the organic layer was concentrated, excessive methanol was added to obtain a product. The product was filtered to obtain the intermediate H-5 (2.7 g).

(3) Host3

The intermediate H-5 (1.3 g, 0.05 mol) and dibenzofuran-2-ylboronic acid (1.26 g, 0.06 mol) were added and dissolved into toluene (30 ml). The mixture solution was stirred under a nitrogen atmosphere. Na₂CO₃ aqueous solution (1 ml), which is formed by dissolving Na₂CO₃ (1.90 g) into distilled water (8 ml), was added into the mixture solution. Pd(PPh₃)₄ (0.125 g, 0.0125 mmol) was further added. The mixture was heated and stirred under a nitrogen atmosphere. After completion of reaction, the organic layer was separated, and methanol was added into the organic layer to precipitate a white solid mixture. The white solid mixture was refined by silica-gel column chromatography using the eluent of chloroform and hexane (volume ratio=1:3) to obtain the compound Host3 (2.30 g).

4. Synthesis of Compound Host4

The intermediate H-5 (1.3 g, 0.05 mol) and 4-(2-dibenzofuranyl)phenylboronic acid (1.74 g, 0.06 mol) were added and dissolved into toluene (30 ml). The mixture solution was stirred under a nitrogen atmosphere. Na₂CO₃ aqueous solution (1 ml), which is formed by dissolving Na₂CO₃ (1.90 g) into distilled water (8 ml), was added into the mixture solution. Pd(PPh₃)₄ (0.125 g, 0.0125 mmol) was further added. The mixture was heated and stirred under a nitrogen atmosphere. After completion of reaction, the organic layer was separated, and methanol was added into the organic layer to precipitate a white solid mixture. The white solid mixture was refined by silica-gel column chromatography using the eluent of chloroform and hexane (volume ratio=1:3) to obtain the compound Host4 (2.30 g).

Synthesis of the Dopant 1. Synthesis of Compound Dopant3-1 (1) Intermediate (I-7)

Under an atmosphere of nitrogen, intermediate (I-H) (10.0 g), bis(4-t-butylphenyl) amine (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-7) (16.0 g).

(2) Dopant3-1

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was dropwisely added in a flask containing intermediate (I-7) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant3-1 was obtained (8.5 g).

2. Synthesis of Compound Dopant3-2 (1) Intermediate (I-U)

Under an atmosphere of nitrogen, 3,4,5-trichloroaniline (12.0 g), d5-bromobenzene (30.0 g), dichlorobis[(di-t-butyl (4-dimethylaminophenyl) phosphino) palladium (Pd-132, 0.43 g) as a palladium catalyst, sodium-t-butoxide (NaOtBu, 14.7 g), and xylene (200 ml) were put in a flask and heated at 120° C. for three hours. After a reaction, water and ethyl acetate were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene/heptane=1/1 (volume ratio)) to obtain intermediate (I-U) (15.0 g).

(2) Intermediate I-V

Under an atmosphere of nitrogen, intermediate (I-U) (15.0 g), bis(4-t-butylphenyl) amine (25.9 g), bis(dibenzylideneacetone) palladium (0.48 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.86 g), sodium-t-butoxide (10.0 g), and xylene (130 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-V) (23.0 g).

(3) Dopant3-2

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (33.5 ml) was dropwisely added in a flask containing intermediate (I-V) (23.0 g) and tert-butylbenzene (250 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 60° C., the mixture was stirred for one hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (13.6 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 7.0 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, an aqueous solution of sodium acetate that had been cooled in an ice bath and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: heated chlorobenzene). The obtained crude product was washed with refluxed heptane and refluxed ethyl acetate, and then was further reprecipitated from chlorobenzene. Thus, the compound Dopant3-2 was obtained (12.9 g).

3. Synthesis of Compound Dopant3-3 (1) Intermediate (I-H)

Under an atmosphere of nitrogen, 3,4,5-trichloroaniline (15.0 g), iodobenzene (46.7 g), dichlorobis[(di-t-butyl (4-dimethylaminophenyl) phosphino) palladium (Pd-132, 0.54 g) as a palladium catalyst, sodium-t-butoxide (NaOtBu, 18.3 g), and xylene (150 ml) were put in a flask and heated at 120° C. for 2 hours. After a reaction, water and ethyl acetate were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-H) (49.7 g).

(2) Intermediate (I-I)

Under an atmosphere of nitrogen, intermediate (I-H) (10.0 g), intermediate (I-E) (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-I) (16.0 g).

(3) Dopant3-3

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was dropwisely added in a flask containing intermediate (I-I) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled sodium acetate aqueous solution and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant3-3 was obtained (8.5 g).

4. Synthesis of Compound Dopant3-4

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was dropwisely added in a flask containing intermediate (I-I) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled sodium acetate aqueous solution and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant3-4 was obtained (0.5 g).

5. Synthesis of Compound Dopant3-5 (1) Intermediate (I-W)

Under an atmosphere of nitrogen, intermediate (I-R) (10.7 g), intermediate (I-U) (6.0 g), bis(dibenzylideneacetone) palladium (0.58 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.82 g), sodium-t-butoxide (4.0 g), and xylene (60 ml) were put in a flask and heated at 100° C. for 1.5 hours. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene), and the obtained solid was washed with cooled heptane to obtain intermediate (I-W) (9.4 g).

(2) Dopant3-5

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (13.8 ml) was dropwisely added in a flask containing intermediate (I-W) (8.6 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was raised to 60° C., and the mixture was stirred for 0.5 hours. Thereafter, a component having a boiling point lower than that of tert-butylbenzene was distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (5.4 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 2.8 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, an aqueous solution of sodium acetate that had been cooled in an ice bath and then ethyl acetate were added thereto, and the mixture was stirred for one hour. A yellow suspension was filtered, and the precipitate was washed twice with methanol and pure water, and again washed with methanol. The yellow crystal was heated and dissolved in chlorobenzene, and then purified with a silica gel short pass column (eluent: heated chlorobenzene). Heptane was added to the crude product and filtered, and then the crystal was washed with heptane to obtain the compound Dopant3-5 (5.9 g).

6. Synthesis of Compound Dopant6-1 (1) Intermediate (I-8)

Under an atmosphere of nitrogen, intermediate (I-H) (10.0 g), bis(4-t-Amylphenyl) amine (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-8) (16.0 g).

(2) Dopant6-1

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was dropwisely added in a flask containing intermediate (I-8) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant6-1 was obtained (8.5 g).

7. Synthesis of Compound Dopant6-2 (1) Intermediate (I-X)

Under an atmosphere of nitrogen, intermediate (I-U) (15.0 g), bis(4-t-amylphenyl) amine (26.0 g), bis(dibenzylideneacetone) palladium (0.48 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.86 g), sodium-t-butoxide (10.0 g), and xylene (130 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-X) (23.0 g).

(2) Dopant6-2

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (33.5 ml) was dropwisely added in a flask containing intermediate (I-X) (23.0 g) and tert-butylbenzene (250 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 60° C., the mixture was stirred for one hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (13.6 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 7.0 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, an aqueous solution of sodium acetate that had been cooled in an ice bath and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: heated chlorobenzene). The obtained crude product was washed with refluxed heptane and refluxed ethyl acetate, and then was further reprecipitated from chlorobenzene. Thus, the compound Dopant6-2 was obtained (12.9 g).

8. Synthesis of Compound Dopant6-3 (1) Intermediate (I-K)

Under an atmosphere of nitrogen, intermediate (I-H) (10.0 g), intermediate (I-J) (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), SPhos (0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-K) (16.0 g).

(2) Dopant6-3

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was dropwisely added in a flask containing intermediate (I-K) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant6-3 was obtained (8.5 g).

9. Synthesis of Compound Dopant6-4

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was dropwisely added in a flask containing intermediate (I-K) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant6-4 was obtained (0.6 g).

10. Synthesis of Compound Dopant6-5 (1) Intermediate (I-Z)

Under an atmosphere of nitrogen, intermediate (I-U) (10.7 g), intermediate (I-Y) (6.0 g), bis(dibenzylideneacetone) palladium (0.58 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.82 g), sodium-t-butoxide (4.0 g), and xylene (60 ml) were put in a flask and heated at 100° C. for 1.5 hours. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene), and the obtained solid was washed with cooled heptane to obtain intermediate (I-Z) (9.4 g).

(2) Dopant6-5

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (13.8 ml) was dropwisely added in a flask containing intermediate (I-Z) (8.6 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition of tert-butyllithium pentane solution, the temperature of the mixture was raised to 60° C., and the mixture was stirred for 0.5 hours. Thereafter, a component having a boiling point lower than that of tert-butylbenzene was distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (5.4 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 2.8 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, an aqueous solution of sodium acetate that had been cooled in an ice bath and then ethyl acetate were added thereto, and the mixture was stirred for one hour. A yellow suspension was filtered, and the precipitate was washed twice with methanol and pure water, and again washed with methanol. The yellow crystal was heated and dissolved in chlorobenzene, and then purified with a silica gel short pass column (eluent: heated chlorobenzene). Heptane was added to the crude product and filtered, and then the crystal was washed with heptane to obtain the compound Dopant6-5 (6.1 g).

11. Synthesis of Compound Dopant5-1 (1) Intermediate (I-10)

Under an atmosphere of nitrogen, intermediate (I-9) (10.0 g), bis(4-t-Butylphenyl) amine (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-10) (16.1 g).

(2) Dopant5-1

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was put in a flask containing intermediate (I-10) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant5-1 was obtained (8.0 g).

12. Synthesis of Compound Dopant5-2 (1) Intermediate (I-12)

Under an atmosphere of nitrogen, intermediate (I-11) (10.0 g), bis(4-t-Butylphenyl) amine (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-12) (16.0 g).

(2) Dopant5-2

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was put in a flask containing intermediate (I-12) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant5-2 was obtained (8.5 g).

13. Synthesis of Compound Dopant5-3 (1) Intermediate (I-13)

Under an atmosphere of nitrogen, intermediate (I-9) (10.0 g), intermediate (I-E) (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-13) (16.5 g).

(2) Dopant5-3

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was put in a flask containing intermediate (I-13) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant5-3 was obtained (8.5 g).

14. Synthesis of Compound Dopant5-4

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was put in a flask containing intermediate (I-13) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant5-4 was obtained (0.5 g).

15. Synthesis of Compound Dopant5-5 (1) Intermediate (I-14)

Under an atmosphere of nitrogen, intermediate (I-11) (10.0 g), intermediate (I-R) (19.5 g), bis(dibenzylideneacetone) palladium (0.33 g), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (SPhos, 0.59 g), sodium-t-butoxide (6.9 g), and xylene (80 ml) were put in a flask and heated at 100° C. for one hour. After a reaction, water and toluene were added to the reaction solution, followed by stirring. Thereafter, the organic layer was separated and washed with water. Thereafter, the organic layer was concentrated to obtain a crude product. The crude product was purified with a silica gel short pass column (eluent: toluene) to obtain intermediate (I-14) (17.5 g).

(2) Dopant5-5

Under an atmosphere of nitrogen, a 1.62 M tert-butyllithium pentane solution (22.1 ml) was put in a flask containing intermediate (I-14) (16.0 g) and tert-butylbenzene (100 ml) at 0° C. After completion of dropwise addition, the temperature of the mixture was increased to 70° C., the mixture was stirred for 0.5 hour, and then components having boiling points lower than that of tert-butylbenzene were distilled off under reduced pressure. The residue was cooled to −50° C., boron tribromide (9.0 g) was added thereto, the temperature of the mixture was raised to room temperature, and the mixture was stirred for 0.5 hours. Thereafter, the mixture was cooled again to 0° C., N,N-diisopropylethylamine (EtNiPr₂, 4.6 g) was added thereto, and the mixture was stirred at room temperature until heat generation was settled. Subsequently, the temperature of the mixture was raised to 100° C., and the mixture was heated and stirred for one hour. The reaction liquid was cooled to room temperature, cooled aqueous solution of sodium acetate and then ethyl acetate were added thereto, and the mixture was partitioned. The organic layer was concentrated, and then purified with a silica gel short pass column (eluent: toluene). The obtained crude product was further reprecipitated from heptane. Thus, the compound Dopant5-5 was obtained (10.0 g).

[Organic Light Emitting Diode]

The anode (ITO, 0.5 mm), the HIL (Formula 5 (97 wt %) and Formula 6 (3 wt %), 100 Å), the HTL (Formula 5, 1000 Å), the EBL (Formula 7, 100 Å), the EML (host (98 wt %) and dopant (2 wt %), 200 Å), the HBL (Formula 8, 100 Å), the EIL (Formula 9 (98 wt %) and Li (2 wt %), 200 Å) and the cathode (Al, 500 Å) was sequentially deposited. An encapsulation film is formed by using an UV curable epoxy and a moisture getter to form the OLED.

1. COMPARATIVE EXAMPLES (1) Comparative Examples 1 to 4 (Ref1 to Ref4)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(2) Comparative Examples 5 to 8 (Ref5 to Ref8)

The compound “Dopant3-2” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(3) Comparative Examples 9 to 12 (Ref9 to Ref12)

The compound “Dopant3-3” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(4) Comparative Examples 13 to 16 (Ref13 to Ref16)

The compound “Dopant3-4” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(5) Comparative Examples 17 to 20 (Ref17 to Ref20)

The compound “Dopant3-5” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

2. EXAMPLES (1) Example 1 (Ex1)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compound “Host1” in Formula 2 is used as the host to form the EML.

(2) Examples 2 to 5 (Ex2 to Ex5)

The compounds “Dopant3-2”, “Dopant3-3”, “Dopant3-4” and “Dopant3-5” in Formula 4 are respectively used as the dopant, and the compound “Host1” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 1 to 20 and Examples 1 to 5 are measured and listed in Table 1.

TABLE 1 EML V cd/A CIE (x, y) T95 [hr] Ref1  Dopant3-1 Host1-1 3.8 4 0.141 0.06 120 Ref2  Dopant3-1 Host1-2 3.81 4.01 0.14 0.061 121 Ex1 Dopant3-1 Host1 3.8 4 0.141 0.06 160 Ref3  Dopant3-1 Host1-3 3.81 3.99 0.141 0.059 122 Ref4  Dopant3-1 Host1-4 3.81 4.02 0.141 0.06 181 Ref5  Dopant3-2 Host1-1 3.8 4 0.141 0.06 119 Ref6  Dopant3-2 Host1-2 3.81 3.99 0.141 0.059 118 Ex2 Dopant3-2 Host1 3.8 4 0.141 0.06 161 Ref7  Dopant3-2 Host1-3 3.81 3.99 0.141 0.059 123 Ref8  Dopant3-2 Host1-4 3.8 4 0.141 0.06 182 Ref9  Dopant3-3 Host1-1 3.8 4.03 0.141 0.061 120 Ref10 Dopant3-3 Host1-2 3.81 3.99 0.141 0.059 123 Ex3 Dopant3-3 Host1 3.8 4 0.141 0.06 162 Ref11 Dopant3-3 Host1-3 3.81 3.99 0.141 0.059 122 Ref12 Dopant3-3 Host1-4 3.81 3.99 0.141 0.059 183 Ref13 Dopant3-4 Host1-1 3.8 4 0.141 0.06 121 Ref14 Dopant3-4 Host1-2 3.81 3.99 0.141 0.059 123 Ex4 Dopant3-4 Host1 3.81 3.99 0.141 0.059 163 Ref15 Dopant3-4 Host1-3 3.8 4 0.141 0.06 124 Ref16 Dopant3-4 Host1-4 3.8 4.03 0.141 0.061 181 Ref17 Dopant3-5 Host1-1 3.81 4.01 0.141 0.061 185 Ref18 Dopant3-5 Host1-2 3.8 4 0.141 0.06 183 Ex5 Dopant3-5 Host1 3.8 4.03 0.141 0.061 250 Ref19 Dopant3-5 Host1-3 3.78 3.98 0.141 0.06 181 Ref20 Dopant3-5 Host1-4 3.81 4.02 0.14 0.06 280

As shown in Table 1, the lifespan of the OLED in Comparative Examples 4, 8, 12, 16 and 20 and Examples 1 to 5 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 4, 8, 12, 16 and 20 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 1 to 5 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 1 to 5 provides sufficient lifespan with less deuterium atoms which is very expensive. Namely, with minimizing the increase of the production cost by the deuterium atom, the OLED provides sufficient lifespan.

In addition, when the EML includes, e.g., the compound Dopant 3-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

3. COMPARATIVE EXAMPLES (1) Comparative Examples 21 to 24 (Ref21 to Ref24)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(2) Comparative Examples 25 to 28 (Ref25 to Ref28)

The compound “Dopant3-2” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(3) Comparative Examples 29 to 32 (Ref29 to Ref32)

The compound “Dopant3-3” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(4) Comparative Examples 33 to 36 (Ref33 to Ref36)

The compound “Dopant3-4” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(5) Comparative Examples 37 to 40 (Ref37 to Ref40)

The compound “Dopant3-5” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

4. EXAMPLES (1) Example 6 (Ex6)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compound “Host2” in Formula 2 is used as the host to form the EML.

(2) Examples 7 to 10 (Ex7 to Ex10)

The compounds “Dopant3-2”, “Dopant3-3”, “Dopant3-4” and “Dopant3-5” in Formula 4 are respectively used as the dopant, and the compound “Host2” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 21 to 40 and Examples 6 to 10 are measured and listed in Table 2.

TABLE 2 EML V cd/A CIE (x, y) T95 [hr] Ref21 Dopant3-1 Host2-1 3.8 4.02 0.141 0.06 121 Ref22 Dopant3-1 Host2-2 3.79 4.01 0.141 0.06 123 Ex6  Dopant3-1 Host2 3.8 4.03 0.141 0.061 165 Ref23 Dopant3-1 Host2-3 3.78 3.98 0.141 0.06 124 Ref24 Dopant3-1 Host2-4 3.81 4.02 0.14 0.06 180 Ref25 Dopant3-2 Host2-1 3.81 4.01 0.14 0.061 120 Ref26 Dopant3-2 Host2-2 3.8 4 0.141 0.06 119 Ex7  Dopant3-2 Host2 3.81 4.01 0.14 0.061 163 Ref27 Dopant3-2 Host2-3 3.8 4 0.141 0.06 121 Ref28 Dopant3-2 Host2-4 3.8 4.02 0.141 0.06 183 Ref29 Dopant3-3 Host2-1 3.78 3.98 0.141 0.06 123 Ref30 Dopant3-3 Host2-2 3.81 4.02 0.14 0.06 123 Ex8  Dopant3-3 Host2 3.81 4.01 0.14 0.061 164 Ref31 Dopant3-3 Host2-3 3.8 4 0.141 0.06 124 Ref32 Dopant3-3 Host2-4 3.8 4 0.141 0.06 181 Ref33 Dopant3-4 Host2-1 3.8 4 0.141 0.06 119 Ref34 Dopant3-4 Host2-2 3.8 4.02 0.141 0.06 122 Ex9  Dopant3-4 Host2 3.78 3.98 0.141 0.06 164 Ref35 Dopant3-4 Host2-3 3.81 4.02 0.14 0.06 123 Ref36 Dopant3-4 Host2-4 3.81 4.01 0.14 0.061 182 Ref37 Dopant3-5 Host2-1 3.8 4 0.141 0.06 183 Ref38 Dopant3-5 Host2-2 3.81 4.01 0.14 0.061 182 Ex10 Dopant3-5 Host2 3.8 4 0.141 0.06 251 Ref39 Dopant3-5 Host2-3 3.8 4.02 0.141 0.06 184 Ref40 Dopant3-5 Host2-4 3.79 4.01 0.141 0.06 275

As shown in Table 2, the lifespan of the OLED in Comparative Examples 24, 28, 32, 36 and 40 and Examples 6 to 10 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 24, 28, 32, 36 and 40 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 6 to 10 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 6 to 10 provides sufficient lifespan with less deuterium atoms which is very expensive.

In addition, when the EML includes, e.g., the compound Dopant 3-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

5. COMPARATIVE EXAMPLES (1) Comparative Examples 41 to 44 (Ref41 to Ref44)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(2) Comparative Examples 45 to 48 (Ref45 to Ref48)

The compound “Dopant3-2” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(3) Comparative Examples 49 to 52 (Ref49 to Ref52)

The compound “Dopant3-3” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(4) Comparative Examples 53 to 56 (Ref53 to Ref56)

The compound “Dopant3-4” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(5) Comparative Examples 57 to 60 (Ref57 to Ref60)

The compound “Dopant3-5” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

6. EXAMPLES (1) Example 11 (Ex11)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compound “Host3” in Formula 2 is used as the host to form the EML.

(2) Examples 12 to 15 (Ex12 to Ex15)

The compounds “Dopant3-2”, “Dopant3-3”, “Dopant3-4” and “Dopant3-5” in Formula 4 are respectively used as the dopant, and the compound “Host3” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 41 to 60 and Examples 11 to 15 are measured and listed in Table 3.

TABLE 3 EML V cd/A CIE (x, y) T95 [hr] Ref41 Dopant3-1 Host3-1 3.75 4.05 0.141 0.06 122 Ref42 Dopant3-1 Host3-2 3.73 4.04 0.141 0.059 123 Ex11 Dopant3-1 Host3 3.75 4.04 0.141 0.06 165 Ref43 Dopant3-1 Host3-3 3.76 4.06 0.141 0.06 128 Ref44 Dopant3-1 Host3-4 3.75 4.05 0.141 0.061 185 Ref45 Dopant3-2 Host3-1 3.75 4.04 0.141 0.06 121 Ref46 Dopant3-2 Host3-2 3.76 4.06 0.141 0.06 119 Ex12 Dopant3-2 Host3 3.75 4.04 0.141 0.06 161 Ref47 Dopant3-2 Host3-3 3.75 4.05 0.141 0.061 124 Ref48 Dopant3-2 Host3-4 3.72 4.09 0.141 0.059 182 Ref49 Dopant3-3 Host3-1 3.73 4.08 0.141 0.06 125 Ref50 Dopant3-3 Host3-2 3.76 4.06 0.141 0.06 124 Ex13 Dopant3-3 Host3 3.75 4.05 0.141 0.061 167 Ref51 Dopant3-3 Host3-3 3.72 4.09 0.141 0.059 122 Ref52 Dopant3-3 Host3-4 3.76 4.06 0.141 0.06 179 Ref53 Dopant3-4 Host3-1 3.75 4.04 0.141 0.06 123 Ref54 Dopant3-4 Host3-2 3.73 4.08 0.141 0.06 122 Ex14 Dopant3-4 Host3 3.75 4.04 0.141 0.06 165 Ref55 Dopant3-4 Host3-3 3.75 4.04 0.141 0.06 121 Ref56 Dopant3-4 Host3-4 3.76 4.06 0.141 0.06 184 Ref57 Dopant3-5 Host3-1 3.72 4.09 0.141 0.059 180 Ref58 Dopant3-5 Host3-2 3.73 4.08 0.141 0.06 182 Ex15 Dopant3-5 Host3 3.75 4.04 0.141 0.06 245 Ref59 Dopant3-5 Host3-3 3.76 4.06 0.141 0.06 187 Ref60 Dopant3-5 Host3-4 3.75 4.05 0.141 0.061 278

As shown in Table 3, the lifespan of the OLED in Comparative Examples 44, 48, 52, 56 and 60 and Examples 11 to 15 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 44, 48, 52, 56 and 60 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 11 to 15 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 11 to 15 provides sufficient lifespan with less deuterium atoms which is very expensive.

In addition, when the EML includes, e.g., the compound Dopant 3-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

7. COMPARATIVE EXAMPLES (1) Comparative Examples 61 to 64 (Ref61 to Ref64)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(2) Comparative Examples 65 to 68 (Ref65 to Ref68)

The compound “Dopant3-2” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(3) Comparative Examples 69 to 72 (Ref69 to Ref72)

The compound “Dopant3-3” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(4) Comparative Examples 73 to 76 (Ref73 to Ref76)

The compound “Dopant3-4” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(5) Comparative Examples 77 to 80 (Ref77 to Ref80)

The compound “Dopant3-5” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

8. EXAMPLES (1) Example 16 (Ex16)

The compound “Dopant3-1” in Formula 4 is used as the dopant, and the compound “Host4” in Formula 2 is used as the host to form the EML.

(2) Examples 17 to 20 (Ex17 to Ex20)

The compounds “Dopant3-2”, “Dopant3-3”, “Dopant3-4” and “Dopant3-5” in Formula 4 are respectively used as the dopant, and the compound “Host4” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 61 to 80 and Examples 16 to 20 are measured and listed in Table 4.

TABLE 4 EML V cd/A CIE (x, y) T95 [hr] Ref61 Dopant3-1 Host4-1 3.72 4.08 0.141 0.06 119 Ref62 Dopant3-1 Host4-2 3.71 4.07 0.141 0.06 121 Ex16 Dopant3-1 Host4 3.73 4.1 0.141 0.06 158 Ref63 Dopant3-1 Host4-3 3.72 4.09 0.141 0.059 123 Ref64 Dopant3-1 Host4-4 3.73 4.08 0.141 0.06 183 Ref65 Dopant3-2 Host4-1 3.71 4.07 0.141 0.06 119 Ref66 Dopant3-2 Host4-2 3.73 4.1 0.141 0.06 118 Ex17 Dopant3-2 Host4 3.73 4.08 0.141 0.06 161 Ref67 Dopant3-2 Host4-3 3.76 4.06 0.141 0.06 120 Ref63 Dopant3-2 Host4-4 3.75 4.05 0.141 0.061 181 Ref69 Dopant3-3 Host4-1 3.72 4.09 0.141 0.059 118 Ref70 Dopant3-3 Host4-2 3.73 4.08 0.141 0.06 119 Ex18 Dopant3-3 Host4 3.76 4.06 0.141 0.06 162 Ref71 Dopant3-3 Host4-3 3.75 4.05 0.141 0.061 121 Ref72 Dopant3-3 Host4-4 3.75 4.05 0.141 0.061 182 Ref73 Dopant3-4 Host4-1 3.73 4.08 0.141 0.06 121 Ref74 Dopant3-4 Host4-2 3.76 4.06 0.141 0.06 123 Ex19 Dopant3-4 Host4 3.75 4.05 0.141 0.061 162 Ref75 Dopant3-4 Host4-3 3.71 4.07 0.141 0.06 121 Ref76 Dopant3-4 Host4-4 3.73 4.1 0.141 0.06 185 Ref77 Dopant3-5 Host4-1 3.75 4.04 0.141 0.06 182 Ref78 Dopant3-5 Host4-2 3.76 4.06 0.141 0.06 183 Ex20 Dopant3-5 Host4 3.75 4.05 0.141 0.061 241 Ref79 Dopant3-5 Host4-3 3.75 4.04 0.141 0.06 179 Ref80 Dopant3-5 Host4-4 3.76 4.06 0.141 0.06 281

As shown in Table 4, the lifespan of the OLED in Comparative Examples 64, 68, 72, 76 and 80 and Examples 17 to 20 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 64, 68, 72, 76 and 80 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 17 to 20 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 17 to 20 provides sufficient lifespan with less deuterium atoms which is very expensive.

In addition, when the EML includes, e.g., the compound Dopant 3-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

9. COMPARATIVE EXAMPLES (1) Comparative Examples 81 to 84 (Ref81 to Ref84)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(2) Comparative Examples 85 to 88 (Ref85 to Ref88)

The compound “Dopant6-2” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(3) Comparative Examples 89 to 92 (Ref89 to Ref92)

The compound “Dopant6-3” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(4) Comparative Examples 93 to 96 (Ref93 to Ref96)

The compound “Dopant6-4” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

(5) Comparative Examples 97 to 100 (Ref97 to Ref100)

The compound “Dopant6-5” in Formula 4 is used as the dopant, and the compounds “Host1-1”, “Host1-2”, “Host1-3” and “Host1-4” in Formula 10 are respectively used as the host to form the EML.

10. EXAMPLES (1) Example 21 (Ex21)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compound “Host1” in Formula 2 is used as the host to form the EML.

(2) Examples 22 to 25 (Ex22 to Ex25)

The compounds “Dopant6-2”, “Dopant6-3”, “Dopant6-4” and “Dopant6-5” in Formula 4 are respectively used as the dopant, and the compound “Host1” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 81 to 100 and Examples 21 to 25 are measured and listed in Table 5.

TABLE 5 EML V cd/A CIE (x, y) T95 [hr] Ref81  Dopant6-1 Host1-1 3.8 4 0.141 0.06 120 Ref82  Dopant6-1 Host1-2 3.81 4.01 0.14 0.061 121 Ex21 Dopant6-1 Host1 3.8 4 0.141 0.06 162 Ref83  Dopant6-1 Host1-3 3.8 4.02 0.141 0.06 122 Ref84  Dopant6-1 Host1-4 3.81 4.01 0.14 0.061 181 Ref85  Dopant6-2 Host1-1 3.81 4.01 0.14 0.061 119 Ref86  Dopant6-2 Host1-2 3.8 4 0.141 0.06 119 Ex22 Dopant6-2 Host1 3.81 4.01 0.14 0.061 162 Ref87  Dopant6-2 Host1-3 3.81 4.01 0.14 0.061 121 Ref88  Dopant6-2 Host1-4 3.8 4 0.141 0.06 182 Ref89  Dopant6-3 Host1-1 3.8 4 0.141 0.06 121 Ref90  Dopant6-3 Host1-2 3.81 4.02 0.14 0.06 120 Ex23 Dopant6-3 Host1 3.81 4.01 0.14 0.061 163 Ref91  Dopant6-3 Host1-3 3.8 4 0.441 0.06 123 Ref92  Dopant6-3 Host1-4 3.8 4 0.141 0.06 185 Ref93  Dopant6-4 Host1-1 3.8 4 0.141 0.06 120 Ref94  Dopant6-4 Host1-2 3.8 4.02 0.141 0.06 121 Ex24 Dopant6-4 Host1 3.78 3.98 0.141 0.06 163 Ref95  Dopant6-4 Host1-3 3.81 4.02 0.14 0.06 122 Ref96  Dopant6-4 Host1-4 3.81 4.01 0.14 0.061 185 Ref97  Dopant6-5 Host1-1 3.8 4 0.141 0.06 181 Ref95  Dopant6-5 Host1-2 3.78 3.98 0.141 0.06 182 Ex25 Dopant6-5 Host1 3.8 4.02 0.141 0.06 247 Ref99  Dopant6-5 Host1-3 3.78 3.98 0.141 0.06 181 Ref100 Dopant6-5 Host1-4 3.79 4.01 0.141 0.06 274

As shown in Table 5, the lifespan of the OLED in Comparative Examples 84, 88, 92, 96 and 100 and Examples 21 to 25 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 84, 88, 92, 96 and 100 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 21 to 25 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 21 to 25 provides sufficient lifespan with less deuterium atoms which is very expensive.

In addition, when the EML includes, e.g., the compound Dopant 6-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

11. COMPARATIVE EXAMPLES (1) Comparative Examples 101 to 104 (Ref101 to Ref104)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(2) Comparative Examples 105 to 108 (Ref105 to Ref108)

The compound “Dopant6-2” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(3) Comparative Examples 109 to 112 (Ref109 to Ref112)

The compound “Dopant6-3” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(4) Comparative Examples 113 to 116 (Ref113 to Ref116)

The compound “Dopant6-4” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

(5) Comparative Examples 117 to 120 (Ref117 to Ref120)

The compound “Dopant6-5” in Formula 4 is used as the dopant, and the compounds “Host2-1”, “Host2-2”, “Host2-3” and “Host2-4” in Formula 11 are respectively used as the host to form the EML.

12. EXAMPLES (1) Example 26 (Ex26)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compound “Host2” in Formula 2 is used as the host to form the EML.

(2) Examples 27 to 30 (Ex27 to Ex30)

The compounds “Dopant6-2”, “Dopant6-3”, “Dopant6-4” and “Dopant6-5” in Formula 4 are respectively used as the dopant, and the compound “Host2” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 101 to 120 and Examples 26 to 30 are measured and listed in Table 6.

TABLE 6 EML V cd/A CIE (x, y) T95 [hr] Ref101 Dopant6-1 Host2-1 3.8 4.03 0.141 0.06 120 Ref102 Dopant6-1 Host2-2 3.8 4.03 0.141 0.061 121 Ex26 Dopant6-1 Host2 3.78 3.98 0.141 0.06 165 Ref103 Dopant6-1 Host2-3 3.81 4.01 0.14 0.061 122 Ref104 Dopant6-1 Host2-4 3.8 4 0.141 0.06 184 Ref105 Dopant6-2 Host2-1 3.8 4.02 0.141 0.06 122 Ref106 Dopant6-2 Host2-2 3.81 4.01 0.14 0.061 119 Ex27 Dopant6-2 Host2 3.8 4 0.141 0.06 164 Ref107 Dopant6-2 Host2-3 3.8 4 0.141 0.06 123 Ref108 Dopant6-2 Host2-4 3.8 4 0.141 0.06 186 Ref109 Dopant6-3 Host2-1 3.81 4.02 0.14 0.06 125 Ref110 Dopant6-3 Host2-2 3.81 4.01 0.14 0.061 124 Ex28 Dopant6-3 Host2 3.8 4 0.141 0.06 167 Ref111 Dopant6-3 Host2-3 3.8 4 0.141 0.06 122 Ref112 Dopant6-3 Host2-4 3.8 4.02 0.141 0.06 184 Ref113 Dopant6-4 Host2-1 3.8 4 0.141 0.06 119 Ref114 Dopant6-4 Host2-2 3.8 4.02 0.141 0.06 121 Ex29 Dopant6-4 Host2 3.78 3.98 0.141 0.06 162 Ref115 Dopant6-4 Host2-3 3.8 4.02 0.141 0.06 123 Ref116 Dopant6-4 Host2-4 3.78 3.98 0.141 0.06 184 Ref117 Dopant6-5 Host2-1 3.81 4.02 0.14 0.06 182 Ref118 Dopant6-5 Host2-2 3.81 4.01 0.14 0.061 183 Ex30 Dopant6-5 Host2 3.8 4 0.141 0.06 249 Ref119 Dopant6-5 Host2-3 3.8 4 0.141 0.06 186 Ref120 Dopant6-5 Host2-4 3.81 4.02 0.14 0.06 280

As shown in Table 6, the lifespan of the OLED in Comparative Examples 104, 108, 112, 116 and 120 and Examples 26 to 30 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 104, 108, 112, 116 and 120 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 26 to 30 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 26 to 30 provides sufficient lifespan with less deuterium atoms which is very expensive.

In addition, when the EML includes, e.g., the compound Dopant 6-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

13. COMPARATIVE EXAMPLES (1) Comparative Examples 121 to 124 (Ref121 to Ref124)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(2) Comparative Examples 125 to 128 (Ref125 to Ref128)

The compound “Dopant6-2” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(3) Comparative Examples 129 to 132 (Ref129 to Ref132)

The compound “Dopant6-3” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(4) Comparative Examples 133 to 136 (Ref133 to Ref136)

The compound “Dopant6-4” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

(5) Comparative Examples 137 to 140 (Ref137 to Ref140)

The compound “Dopant6-5” in Formula 4 is used as the dopant, and the compounds “Host3-1”, “Host3-2”, “Host3-3” and “Host3-4” in Formula 12 are respectively used as the host to form the EML.

14. EXAMPLES (1) Example 31 (Ex31)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compound “Host3” in Formula 2 is used as the host to form the EML.

(2) Examples 32 to 35 (Ex32 to Ex35)

The compounds “Dopant6-2”, “Dopant6-3”, “Dopant6-4” and “Dopant6-5” in Formula 4 are respectively used as the dopant, and the compound “Host3” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 121 to 140 and Examples 31 to 35 are measured and listed in Table 7.

TABLE 7 EML V cd/A CIE (x, y) T95 [hr] Ref121 Dopant6-1 Host3-1 3.75 4.06 0.141 0.06 120 Ref122 Dopant6-1 Host3-2 3.71 4.07 0.141 0.06 121 Ex31 Dopant6-1 Host3 3.73 4.1 0.141 0.06 163 Ref123 Dopant6-1 Host3-3 3.72 4.09 0.141 0.059 123 Ref124 Dopant6-1 Host3-4 3.73 4.08 0.141 0.06 185 Ref125 Dopant6-2 Host3-1 3.71 4.07 0.141 0.06 120 Ref126 Dopant6-2 Host3-2 3.73 4.1 0.141 0.06 122 Ex32 Dopant6-2 Host3 3.73 4.08 0.141 0.06 162 Ref127 Dopant6-2 Host3-3 3.76 4.06 0.141 0.06 121 Ref128 Dopant6-2 Host3-4 3.75 4.05 0.141 0.061 184 Ref129 Dopant6-3 Host3-1 3.72 4.09 0.141 0.059 123 Ref130 Dopant6-3 Host3-2 3.73 4.08 0.141 0.06 119 Ex33 Dopant6-3 Host3 3.76 4.06 0.141 0.06 163 Ref131 Dopant6-3 Host3-3 3.75 4.05 0.141 0.061 122 Ref132 Dopant6-3 Host3-4 3.75 4.05 0.141 0.061 181 Ref133 Dopant6-4 Host3-1 3.72 4.09 0.141 0.059 122 Ref134 Dopant6-4 Host3-2 3.76 4.06 0.141 0.06 119 Ex34 Dopant6-4 Host3 3.75 4.04 0.141 0.06 161 Ref135 Dopant6-4 Host3-3 3.73 4.08 0.141 0.06 123 Ref136 Dopant6-4 Host3-4 3.75 4.04 0.141 0.06 182 Ref137 Dopant6-5 Host3-1 3.75 4.04 0.141 0.06 180 Ref138 Dopant6-5 Host3-2 3.76 4.06 0.141 0.06 182 Ex35 Dopant6-5 Host3 3.72 4.09 0.141 0.059 246 Ref139 Dopant6-5 Host3-3 3.73 4.08 0.141 0.06 183 Ref140 Dopant6-5 Host3-4 3.75 4.04 0.141 0.06 277

As shown in Table 7, the lifespan of the OLED in Comparative Examples 124, 128, 132, 136 and 140 and Examples 31 to 35 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 124, 128, 132, 136 and 140 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 31 to 35 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 31 to 35 provides sufficient lifespan with less deuterium atoms which is very expensive.

In addition, when the EML includes, e.g., the compound Dopant 6-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

15. COMPARATIVE EXAMPLES (1) Comparative Examples 141 to 144 (Ref141 to Ref144)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(2) Comparative Examples 145 to 148 (Ref145 to Ref148)

The compound “Dopant6-2” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(3) Comparative Examples 149 to 152 (Ref149 to Ref152)

The compound “Dopant6-3” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(4) Comparative Examples 153 to 156 (Ref153 to Ref156)

The compound “Dopant6-4” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

(5) Comparative Examples 157 to 160 (Ref157 to Ref160)

The compound “Dopant6-5” in Formula 4 is used as the dopant, and the compounds “Host4-1”, “Host4-2”, “Host4-3” and “Host4-4” in Formula 13 are respectively used as the host to form the EML.

16. EXAMPLES (1) Example 36 (Ex36)

The compound “Dopant6-1” in Formula 4 is used as the dopant, and the compound “Host4” in Formula 2 is used as the host to form the EML.

(2) Examples 37 to 40 (Ex37 to Ex40)

The compounds “Dopant6-2”, “Dopant6-3”, “Dopant6-4” and “Dopant6-5” in Formula 4 are respectively used as the dopant, and the compound “Host4” in Formula 2 is used as the host to form the EML.

The properties, i.e., voltage (V), efficiency (Cd/A), color coordinate (CIE) and lifespan (T95), of the OLEDs manufactured in Comparative Examples 141 to 160 and Examples 36 to 40 are measured and listed in Table 8.

TABLE 8 EML V cd/A CIE (x, y) T95 [hr] Ref141 Dopant6-1 Host4-1 3.72 4.07 0.141 0.06 120 Ref142 Dopant6-1 Host4-2 3.71 4.07 0.141 0.06 121 Ex36 Dopant6-1 Host4 3.73 4.1 0.141 0.06 162 Ref143 Dopant6-1 Host4-3 3.73 4.08 0.141 0.06 122 Ref144 Dopant6-1 Host4-4 3.76 4.06 0.141 0.06 181 Ref145 Dopant6-2 Host4-1 3.75 4.05 0.141 0.061 121 Ref146 Dopant6-2 Host4-2 3.72 4.09 0.141 0.059 122 Ex37 Dopant6-2 Host4 3.73 4.08 0.141 0.06 163 Ref147 Dopant6-2 Host4-3 3.76 4.06 0.141 0.06 119 Ref148 Dopant6-2 Host4-4 3.75 4.05 0.141 0.061 184 Ref149 Dopant6-3 Host4-1 3.75 4.05 0.141 0.061 122 Ref150 Dopant6-3 Host4-2 3.71 4.07 0.141 0.06 123 Ex38 Dopant6-3 Host4 3.73 4.1 0.141 0.06 161 Ref151 Dopant6-3 Host4-3 3.72 4.09 0.141 0.059 121 Ref152 Dopant6-3 Host4-4 3.73 4.08 0.141 0.06 185 Ref153 Dopant6-4 Host4-1 3.71 4.07 0.141 0.06 121 Ref154 Dopant6-4 Host4-2 3.73 4.1 0.141 0.06 123 Ex39 Dopant6-4 Host4 3.73 4.08 0.141 0.06 163 Ref155 Dopant6-4 Host4-3 3.76 4.06 0.141 0.06 120 Ref156 Dopant6-4 Host4-4 3.76 4.06 0.141 0.06 181 Ref157 Dopant6-5 Host4-1 3.75 4.05 0.141 0.061 182 Ref158 Dopant6-5 Host4-2 3.75 4.05 0.141 0.061 181 Ex40 Dopant6-5 Host4 3.71 4.07 0.141 0.06 248 Ref159 Dopant6-5 Host4-3 3.73 4.1 0.141 0.06 185 Ref160 Dopant6-5 Host4-4 3.72 4.09 0.141 0.059 275

As shown in Table 8, the lifespan of the OLED in Comparative Examples 144, 148, 152, 156 and 160 and Examples 36 to 40 using the host, the core of which is substituted with deuterium, is significantly increased.

On the other hand, in comparison to the OLED in Comparative Examples 144, 148, 152, 156 and 160 using the host, the core and the substituent of which are substituted with deuterium, the lifespan of the OLED in Examples 36 to 40 using the host, only the core of which is substituted with deuterium, is little short. However, the OLED in Examples 36 to 40 provides sufficient lifespan with less deuterium atoms which is very expensive.

In addition, when the EML includes, e.g., the compound Dopant 6-5 as the dopant, the lifespan of the OLED is significantly increased.

Moreover, when each of the HIL and the HTL includes the compound of Formula 5 and the EBL includes the compound of Formula 7, the properties of the OLED are improved.

In the OLED D of the present disclosure, since the EML 240 includes the host 242 of the anthracene derivative, the core of which is deuterated, and the dopant 244 of the boron dopant, the OLED D and the organic light emitting display device 100 have advantages in the emitting efficiency, the lifespan and the production cost. In addition, the boron derivative as the dopant 244 in the EML 240 is deuterated, the lifespan of the OLED D and the organic light emitting display device 100 is further increased.

FIG. 4 is a schematic cross-sectional view illustrating an OLED having a tandem structure of two emitting parts according to the first embodiment of the present disclosure.

As shown in FIG. 4, the OLED D includes the first and second electrodes 160 and 164 facing each other and the organic emitting layer 162 between the first and second electrodes 160 and 164. The organic emitting layer 162 includes a first emitting part 310 including a first EML 320, a second emitting part 330 including a second EML 340 and a charge generation layer (CGL) 350 between the first and second emitting parts 310 and 330.

The first electrode 160 may be formed of a conductive material having a relatively high work function to serve as an anode for injecting a hole into the organic emitting layer 162. The second electrode 164 may be formed of a conductive material having a relatively low work function to serve as a cathode for injecting an electron into the organic emitting layer 162.

The CGL 350 is positioned between the first and second emitting parts 310 and 330, and the first emitting part 310, the CGL 350 and the second emitting part 330 are sequentially stacked on the first electrode 160. Namely, the first emitting part 310 is positioned between the first electrode 160 and the CGL 350, and the second emitting part 330 is positioned between the second electrode 164 and the CGL 350.

The first emitting part 310 includes a first EML 320. In addition, the first emitting part 310 may further include a first EBL 316 between the first electrode 160 and the first EML 320 and a first HBL 318 between the first EML 320 and the CGL 350.

In addition, the first emitting part 310 may further include a first HTL 314 between the first electrode 160 and the first EBL 316 and an HIL 312 between the first electrode 160 and the first HTL 314.

The first EML 320 includes a host 322 of the anthracene derivative and the dopant 324 of the boron derivative, and the anthracene core of the anthracene derivative is deuterated. The first EML 320 emits blue light.

For example, in the first EML 320, the anthracene core of the host 322 is deuterated, and the dopant 324 may not be deuterated or may be partially or entirely deuterated.

In the first EML 320, the host 322 may have a weight % of about 70 to 99.9, and the dopant 324 may have a weight % of about 0.1 to 30. To provide sufficient emitting efficiency, the dopant 324 may have a weight % of about 0.1 to 10, preferably about 1 to 5.

The second emitting part 330 includes the second EML 340. In addition, the second emitting part 330 may further include a second EBL 334 between the CGL 350 and the second EML 340 and a second HBL 336 between the second EML 340 and the second electrode 164.

In addition, the second emitting part 330 may further include a second HTL 332 between the CGL 350 and the second EBL 334 and an EIL 338 between the second HBL 336 and the second electrode 164.

The second EML 340 includes a host 342 of the anthracene derivative and a dopant 344 of the boron derivative, and the anthracene core of the anthracene derivative is deuterated. The second EML 340 emits blue light.

For example, in the second EML 340, the anthracene core of the host 342 is deuterated, and the dopant 344 may not be deuterated or may be partially or entirely deuterated.

In the second EML 340, the host 342 may have a weight % of about 70 to 99.9, and the dopant 344 may have a weight % of about 0.1 to 30. To provide sufficient emitting efficiency, the dopant 344 may have a weight % of about 0.1 to 10, preferably about 1 to 5.

The host 342 of the second EML 340 may be same as or different from the host 322 of the first EML 320, and the dopant 344 of the second EML 340 may be same as or different from the dopant 324 of the first EML 320.

The CGL 350 is positioned between the first and second emitting parts 310 and 330. Namely, the first and second emitting parts 310 and 330 are connected through the CGL 350. The CGL 350 may be a P-N junction CGL of an N-type CGL 352 and a P-type CGL 354.

The N-type CGL 352 is positioned between the first HBL 318 and the second HTL 332, and the P-type CGL 354 is positioned between the N-type CGL 352 and the second HTL 332.

In the OLED D, each of the first and second EMLs 320 and 340 includes the host 322 and 342, each of which is the anthracene derivative, and the dopant 324 and 344, each of which is the boron derivative, and the anthracene core of the anthracene derivative is deuterated. As a result, the OLED D and the organic light emitting display device 100 have advantages in the emitting efficiency, the lifespan and the production cost.

In addition, since the first and second emitting parts 310 and 330 for emitting blue light are stacked, the organic light emitting display device 100 provides an image having high color temperature.

FIG. 5 is a schematic cross-sectional view illustrating an organic light emitting display device according to a second embodiment of the present disclosure, and FIG. 6 is a schematic cross-sectional view illustrating an OLED having a tandem structure of two emitting parts according to the second embodiment of the present disclosure. FIG. 7 is a schematic cross-sectional view illustrating an OLED having a tandem structure of three emitting parts according to the second embodiment of the present disclosure.

As shown in FIG. 5, the organic light emitting display device 400 includes a first substrate 410, where a red pixel RP, a green pixel GP and a blue pixel BP are defined, a second substrate 470 facing the first substrate 410, an OLED D, which is positioned between the first and second substrates 410 and 470 and providing white emission, and a color filter layer 480 between the OLED D and the second substrate 470.

Each of the first and second substrates 410 and 470 may be a glass substrate or a plastic substrate. For example, each of the first and second substrates 410 and 470 may be a polyimide substrate.

A buffer layer 420 is formed on the first substrate, and the TFT Tr corresponding to each of the red, green and blue pixels RP, GP and BP is formed on the buffer layer 420. The buffer layer 420 may be omitted.

A semiconductor layer 422 is formed on the buffer layer 420. The semiconductor layer 422 may include an oxide semiconductor material or polycrystalline silicon.

A gate insulating layer 424 is formed on the semiconductor layer 422. The gate insulating layer 424 may be formed of an inorganic insulating material such as silicon oxide or silicon nitride.

A gate electrode 430, which is formed of a conductive material, e.g., metal, is formed on the gate insulating layer 424 to correspond to a center of the semiconductor layer 422.

An interlayer insulating layer 432, which is formed of an insulating material, is formed on the gate electrode 430. The interlayer insulating layer 432 may be formed of an inorganic insulating material, e.g., silicon oxide or silicon nitride, or an organic insulating material, e.g., benzocyclobutene or photo-acryl.

The interlayer insulating layer 432 includes first and second contact holes 434 and 436 exposing both sides of the semiconductor layer 422. The first and second contact holes 434 and 436 are positioned at both sides of the gate electrode 430 to be spaced apart from the gate electrode 430.

A source electrode 440 and a drain electrode 442, which are formed of a conductive material, e.g., metal, are formed on the interlayer insulating layer 432.

The source electrode 440 and the drain electrode 442 are spaced apart from each other with respect to the gate electrode 430 and respectively contact both sides of the semiconductor layer 422 through the first and second contact holes 434 and 436.

The semiconductor layer 422, the gate electrode 430, the source electrode 440 and the drain electrode 442 constitute the TFT Tr. The TFT Tr serves as a driving element. Namely, the TFT Tr may correspond to the driving TFT Td (of FIG. 1).

Although not shown, the gate line and the data line cross each other to define the pixel, and the switching TFT is formed to be connected to the gate and data lines. The switching TFT is connected to the TFT Tr as the driving element.

In addition, the power line, which may be formed to be parallel to and spaced apart from one of the gate and data lines, and the storage capacitor for maintaining the voltage of the gate electrode of the TFT Tr in one frame may be further formed.

A passivation layer 450, which includes a drain contact hole 452 exposing the drain electrode 442 of the TFT Tr, is formed to cover the TFT Tr.

A first electrode 460, which is connected to the drain electrode 442 of the TFT Tr through the drain contact hole 452, is separately formed in each pixel. The first electrode 460 may be an anode and may be formed of a conductive material having a relatively high work function. For example, the first electrode 460 may be formed of a transparent conductive material such as indium-tin-oxide (ITO) or indium-zinc-oxide (IZO).

A reflection electrode or a reflection layer may be formed under the first electrode 460. For example, the reflection electrode or the reflection layer may be formed of aluminum-palladium-copper (APC) alloy.

A bank layer 466 is formed on the passivation layer 450 to cover an edge of the first electrode 460. Namely, the bank layer 466 is positioned at a boundary of the pixel and exposes a center of the first electrode 460 in the red, green and blue pixels RP, GP and BP. The bank layer 466 may be omitted.

An organic emitting layer 462 is formed on the first electrode 460.

Referring to FIG. 6, the OLED D includes the first and second electrodes 460 and 464 facing each other and the organic emitting layer 462 between the first and second electrodes 460 and 464. The organic emitting layer 462 includes a first emitting part 710 including a first EML 720, a second emitting part 730 including a second EML 740 and a charge generation layer (CGL) 750 between the first and second emitting parts 710 and 730.

The first electrode 460 may be formed of a conductive material having a relatively high work function to serve as an anode for injecting a hole into the organic emitting layer 462. The second electrode 464 may be formed of a conductive material having a relatively low work function to serve as a cathode for injecting an electron into the organic emitting layer 462.

The CGL 750 is positioned between the first and second emitting parts 710 and 730, and the first emitting part 710, the CGL 750 and the second emitting part 730 are sequentially stacked on the first electrode 460. Namely, the first emitting part 710 is positioned between the first electrode 460 and the CGL 750, and the second emitting part 730 is positioned between the second electrode 464 and the CGL 750.

The first emitting part 710 includes a first EML 720. In addition, the first emitting part 710 may further include a first EBL 716 between the first electrode 460 and the first EML 720 and a first HBL 718 between the first EML 720 and the CGL 750.

In addition, the first emitting part 710 may further include a first HTL 714 between the first electrode 460 and the first EBL 716 and an HIL 712 between the first electrode 460 and the first HTL 714.

The first EML 720 includes a host 722 of the anthracene derivative and the dopant 724 of the boron derivative, and the anthracene core of the anthracene derivative is deuterated. The first EML 720 emits blue light.

For example, in the first EML 720, the anthracene core of the host 722 is deuterated, and the dopant 724 may not be deuterated or may be partially or entirely deuterated.

In the first EML 720, the host 722 may have a weight % of about 70 to 99.9, and the dopant 724 may have a weight % of about 0.1 to 30. To provide sufficient emitting efficiency, the dopant 724 may have a weight % of about 0.1 to 10, preferably about 1 to 5.

The second emitting part 730 includes the second EML 740. In addition, the second emitting part 730 may further include a second EBL 734 between the CGL 750 and the second EML 740 and a second HBL 736 between the second EML 740 and the second electrode 464.

In addition, the second emitting part 730 may further include a second HTL 732 between the CGL 750 and the second EBL 734 and an EIL 738 between the second HBL 736 and the second electrode 464.

The second EML 740 may be a yellow-green EML. For example, the second EML 740 may include a host 742 and a yellow-green dopant 744. The yellow-green dopant 744 may be one of a fluorescent compound, a phosphorescent compound and a delayed fluorescent compound.

In the second EML 740, the host 742 may have a weight % of about 70 to 99.9, and the yellow-green dopant 744 may have a weight % of about 0.1 to 30. To provide sufficient emitting efficiency, the yellow-green dopant 744 may have a weight % of about 0.1 to 10, preferably about 1 to 5.

The CGL 750 is positioned between the first and second emitting parts 710 and 730. Namely, the first and second emitting parts 710 and 730 are connected through the CGL 750. The CGL 750 may be a P-N junction CGL of an N-type CGL 752 and a P-type CGL 754.

The N-type CGL 752 is positioned between the first HBL 718 and the second HTL 732, and the P-type CGL 754 is positioned between the N-type CGL 752 and the second HTL 732.

In FIG. 6, the first EML 720, which is positioned between the first electrode 460 and the CGL 750, includes the host 722 of the anthracene derivative and the dopant 724 of the boron derivative, and the second EML 740, which is positioned between the second electrode 464 and the CGL 750, is the yellow-green EML. Alternatively, the first EML 720, which is positioned between the first electrode 460 and the CGL 750, may be the yellow-green EML, and the second EML 740, which is positioned between the second electrode 464 and the CGL 750, may include the host of the anthracene derivative and the dopant of the boron derivative to be a blue EML.

In the OLED D, the first EML 720 includes the host 722, which is the anthracene derivative, and the dopant 724, which is the boron derivative, and the anthracene core of the anthracene derivative is deuterated. As a result, the OLED D and the organic light emitting display device 400 have advantages in the emitting efficiency, the lifespan and the production cost.

The OLED D including the first emitting part 710 and the second emitting part 730, which provides a yellow-green emission, emits a white light.

Referring to FIG. 7, the organic emitting layer 462 includes a first emitting part 530 including a first EML 520, a second emitting part 550 including a second EML 540, a third emitting part 570 including a third EML 560, a first CGL 580 between the first and second emitting parts 530 and 550 and a second CGL 590 between the second and third emitting parts 550 and 570.

The first electrode 460 may be formed of a conductive material having a relatively high work function to serve as an anode for injecting a hole into the organic emitting layer 462. The second electrode 464 may be formed of a conductive material having a relatively low work function to serve as a cathode for injecting an electron into the organic emitting layer 462.

The first CGL 580 is positioned between the first and second emitting parts 530 and 550, and the second CGL 590 is positioned between the second and third emitting parts 550 and 570. Namely, the first emitting part 530, the first CGL 580, the second emitting part 550, the second CGL 590 and the third emitting part 570 are sequentially stacked on the first electrode 460. In other words, the first emitting part 530 is positioned between the first electrode 460 and the first CGL 580, the second emitting part 550 is positioned between the first and second CGLs 580 and 590, and the third emitting part 570 is positioned between the second electrode 464 and the second CGL 590.

The first emitting part 530 may include an HIL 532, a first HTL 534, a first EBL 536, the first EML 520 and a first HBL 538 sequentially stacked on the first electrode 460. Namely, the HIL 532, the first HTL 534 and the first EBL 536 are positioned between the first electrode 460 and the first EML 520, and the first HBL 538 is positioned between the first EML 520 and the first CGL 580.

The first EML 520 includes a host 522 of the anthracene derivative and the dopant 524 of the boron derivative, and the anthracene core of the anthracene derivative is deuterated. The first EML 520 emits blue light.

For example, in the first EML 520, the anthracene core of the host 522 is deuterated, and the dopant 524 may not be deuterated or may be partially or entirely deuterated.

In the first EML 520, the host 522 may have a weight % of about 70 to 99.9, and the dopant 524 may have a weight % of about 0.1 to 30. To provide sufficient emitting efficiency, the dopant 524 may have a weight % of about 0.1 to 10, preferably about 1 to 5.

The second emitting part 550 may include a second HTL 552, the second EML 540 and an electron transporting layer (ETL) 554. The second HTL 552 is positioned between the first CGL 580 and the second EML 540, and the ETL 554 is positioned between the second EML 540 and the second CGL 590.

The second EML 540 may be a yellow-green EML. For example, the second EML 540 may include a host and a yellow-green dopant. Alternatively, the second EML 540 may include a host, a red dopant and a green dopant. In this instance, the second EML 540 may include a lower layer including the host and the red dopant (or the green dopant) and an upper layer including the host and the green dopant (or the red dopant).

The second EML 540 may have a double-layered structure of a first layer, which includes a host and a red dopant, and a second layer, which includes a host and a yellow-green dopant, or a triple-layered structure of a first layer, which includes a host and a red dopant, a second layer, which includes a host and a yellow-green dopant, and a third layer, which includes a host and a green dopant.

The third emitting part 570 may include a third HTL 572, a second EBL 574, the third EML 560, a second HBL 576 and an EIL 578.

The third EML 560 includes a host 562 of the anthracene derivative and the dopant 564 of the boron derivative, and the anthracene core of the anthracene derivative is deuterated. The third EML 560 emits blue light.

For example, in the third EML 560, the anthracene core of the host 562 is deuterated, and the dopant 564 may not be deuterated or may be partially or entirely deuterated.

In the third EML 560, the host 562 may have a weight % of about 70 to 99.9, and the dopant 564 may have a weight % of about 0.1 to 30. To provide sufficient emitting efficiency, the dopant 564 may have a weight % of about 0.1 to 10, preferably about 1 to 5.

The host 562 of the third EML 560 may be same as or different from the host 522 of the first EML 520, and the dopant 564 of the third EML 560 may be same as or different from the dopant 524 of the first EML 520.

The first CGL 580 is positioned between the first emitting part 530 and the second emitting part 550, and the second CGL 590 is positioned between the second emitting part 550 and the third emitting part 570. Namely, the first and second emitting parts 530 and 550 are connected through the first CGL 580, and the second and third emitting parts 550 and 570 are connected through the second CGL 590. The first CGL 580 may be a P-N junction CGL of a first N-type CGL 582 and a first P-type CGL 584, and the second CGL 590 may be a P-N junction CGL of a second N-type CGL 592 and a second P-type CGL 594.

In the first CGL 580, the first N-type CGL 582 is positioned between the first HBL 538 and the second HTL 552, and the first P-type CGL 584 is positioned between the first N-type CGL 582 and the second HTL 552.

In the second CGL 590, the second N-type CGL 592 is positioned between the ETL 554 and the third HTL 572, and the second P-type CGL 594 is positioned between the second N-type CGL 592 and the third HTL 572.

In the OLED D, each of the first and third EMLs 520 and 560 includes the host 522 and 562, each of which is the anthracene derivative, and the dopant 524 and 564, each of which is the boron derivative, and the anthracene core of the anthracene derivative is deuterated.

Accordingly, the OLED D including the first and third emitting parts 530 and 570 with the second emitting part 550, which emits yellow-green light or red/green light, can emit white light.

In FIG. 7, the OLED D has a triple-stack structure of the first, second and third emitting parts 530, 550 and 570. Alternatively, the OLED D may further include additional emitting part and CGL.

Referring to FIG. 5 again, a second electrode 464 is formed over the substrate 410 where the organic emitting layer 462 is formed.

In the organic light emitting display device 400, since the light emitted from the organic emitting layer 462 is incident to the color filter layer 480 through the second electrode 464, the second electrode 464 has a thin profile for transmitting the light.

The first electrode 460, the organic emitting layer 462 and the second electrode 464 constitute the OLED D.

The color filter layer 480 is positioned over the OLED D and includes a red color filter 482, a green color filter 484 and a blue color filter 486 respectively corresponding to the red, green and blue pixels RP, GP and BP.

Although not shown, the color filter layer 480 may be attached to the OLED D by using an adhesive layer. Alternatively, the color filter layer 480 may be formed directly on the OLED D.

An encapsulation film (not shown) may be formed to prevent penetration of moisture into the OLED D. For example, the encapsulation film may include a first inorganic insulating layer, an organic insulating layer and a second inorganic insulating layer sequentially stacked, but it is not limited thereto. The encapsulation film may be omitted.

A polarization plate (not shown) for reducing an ambient light reflection may be disposed over the top-emission type OLED D. For example, the polarization plate may be a circular polarization plate.

In FIG. 5, the light from the OLED D passes through the second electrode 464, and the color filter layer 480 is disposed on or over the OLED D. Alternatively, when the light from the OLED D passes through the first electrode 460, the color filter layer 480 may be disposed between the OLED D and the first substrate 410.

A color conversion layer (not shown) may be formed between the OLED D and the color filter layer 480. The color conversion layer may include a red color conversion layer, a green color conversion layer and a blue color conversion layer respectively corresponding to the red, green and blue pixels RP, GP and BP. The white light from the OLED D is converted into the red light, the green light and the blue light by the red, green and blue color conversion layer, respectively.

As described above, the white light from the organic light emitting diode D passes through the red color filter 482, the green color filter 484 and the blue color filter 486 in the red pixel RP, the green pixel GP and the blue pixel BP such that the red light, the green light and the blue light are provided from the red pixel RP, the green pixel GP and the blue pixel BP, respectively.

In FIGS. 5 to 7, the OLED D emitting the white light is used for a display device. Alternatively, the OLED D may be formed on an entire surface of a substrate without at least one of the driving element and the color filter layer to be used for a lightening device. The display device and the lightening device each including the OLED D of the present disclosure may be referred to as an organic light emitting device.

FIG. 8 is a schematic cross-sectional view illustrating an organic light emitting display device according to a third embodiment of the present disclosure.

As shown in FIG. 8, the organic light emitting display device 600 includes a first substrate 610, where a red pixel RP, a green pixel GP and a blue pixel BP are defined, a second substrate 670 facing the first substrate 610, an OLED D, which is positioned between the first and second substrates 610 and 670 and providing white emission, and a color conversion layer 680 between the OLED D and the second substrate 670.

Although not shown, a color filter may be formed between the second substrate 670 and each color conversion layer 680.

A TFT Tr, which corresponding to each of the red, green and blue pixels RP, GP and BP, is formed on the first substrate 610, and a passivation layer 650, which has a drain contact hole 652 exposing an electrode, e.g., a drain electrode, of the TFT Tr is formed to cover the TFT Tr.

The OLED D including a first electrode 660, an organic emitting layer 662 and a second electrode 664 is formed on the passivation layer 650. In this instance, the first electrode 660 may be connected to the drain electrode of the TFT Tr through the drain contact hole 652.

An bank layer 666 covering an edge of the first electrode 660 is formed at a boundary of the red, green and blue pixel RP, GP and BP regions.

The OLED D emits a blue light and may have a structure shown in FIG. 3 or FIG. 4. Namely, the OLED D is formed in each of the red, green and blue pixels RP, GP and BP and provides the blue light.

The color conversion layer 680 includes a first color conversion layer 682 corresponding to the red pixel RP and a second color conversion layer 684 corresponding to the green pixel GP. For example, the color conversion layer 680 may include an inorganic color conversion material such as a quantum dot.

The blue light from the OLED D is converted into the red light by the first color conversion layer 682 in the red pixel RP, and the blue light from the OLED D is converted into the green light by the second color conversion layer 684 in the green pixel GP.

Accordingly, the organic light emitting display device 600 can display a full-color image.

On the other hand, when the light from the OLED D passes through the first substrate 610, the color conversion layer 680 is disposed between the OLED D and the first substrate 610.

It will be apparent to those skilled in the art that various modifications and variations can be made in the embodiments of the present disclosure without departing from the spirit or scope of the present disclosure. Thus, it is intended that the modifications and variations cover this disclosure provided they come within the scope of the appended claims and their equivalents. 

What is claimed is:
 1. An organic light emitting device, comprising: a substrate; and an organic light emitting diode positioned on the substrate and including a first electrode; a second electrode facing the first electrode; and a first emitting material layer including a first host of an anthracene derivative and a first dopant of a boron derivative and positioned between the first and second electrodes, wherein an anthracene core of the first host is deuterated, and the first dopant is represented by Formula 3:

wherein each of R₁₁ to R₁₄, each of R₂₁ to R₂₄, each of R₃₁ to R₃₅ and each of R₄₁ to R₄₅ is selected from the group of hydrogen, deuterium, C1 to C10 alkyl, C6 to C30 aryl, C6 to C30 arylamino group and C5 to C30 heteroaryl, and wherein R₅₁ is selected from the group consisting of C12 to C30 arylamino group unsubstituted or substituted with at least one of deuterium and C1 to C10 alkyl and non-substituted or deuterated C5 to C30 heteroaryl.
 2. The organic light emitting device of claim 1, wherein the first dopant is a compound being one of the followings of Formula 4:


3. The organic light emitting device of claim 1, wherein the first host is represented by Formula 1:

wherein each of R₁ and R₂ is independently C6˜C30 aryl group or C5˜C30 heteroaryl group, wherein each of L₁ and L₂ is independently C6-C30 arylene group, and wherein x is an integer of 1 to 8, and each of y1 and y2 is an integer of 0 or
 1. 4. The organic light emitting device of claim 3, wherein the first host is a compound being one of the followings of Formula 2:


5. The organic light emitting device of claim 1, wherein the organic light emitting diode further includes: a second emitting material layer including a second host of an anthracene derivative and a second dopant of a boron derivative and positioned between the first emitting material layer and the second electrode; and a first charge generation layer between the first and second emitting material layers.
 6. The organic light emitting device of claim 5, wherein an anthracene core of the second host is deuterated.
 7. The organic light emitting device of claim 1, wherein the organic light emitting diode further includes: a second emitting material layer emitting a blue light and positioned between the first emitting material layer and the second electrode; and a first charge generation layer between the first and second emitting material layers.
 8. The organic light emitting device of claim 1, wherein a red pixel, a green pixel and a blue pixel are defined on the substrate, and the organic light emitting diode corresponds to each of the red, green and blue pixels, and wherein the organic light emitting device further includes: a color conversion layer disposed between the substrate and the organic light emitting diode or on the organic light emitting diode and corresponding to the red and green pixels.
 9. The organic light emitting device of claim 5, wherein the organic light emitting diode further includes: a third emitting material layer emitting a yellow-green light and positioned between the first charge generation layer and the second emitting material layer; and a second charge generation layer between the second and third emitting material layers.
 10. The organic light emitting device of claim 5, wherein the organic light emitting diode further includes: a third emitting material layer emitting a red light and a green light and positioned between the first charge generation layer and the second emitting material layer; and a second charge generation layer between the second and third emitting material layers.
 11. The organic light emitting device of claim 5, wherein the organic light emitting diode further includes: a third emitting material layer including a first layer and a second layer and positioned between the first charge generation layer and the second emitting material layer, wherein the first layer emits a red light, and the second layer emits a yellow-green light; and a second charge generation layer between the second and third emitting material layers.
 12. The organic light emitting device of claim 11, wherein the third emitting material layer further includes a third layer emitting a green light.
 13. The organic light emitting device of claim 1, wherein the organic light emitting diode further includes: a second emitting material layer emitting a yellow-green light and positioned between the first emitting material layer and the second electrode; and a first charge generation layer between the first and second emitting material layers.
 14. The organic light emitting device of claim 9, wherein a red pixel, a green pixel and a blue pixel are defined on the substrate, and the organic light emitting diode corresponds to each of the red, green and blue pixels, and wherein the organic light emitting device further includes: a color filter layer disposed between the substrate and the organic light emitting diode or on the organic light emitting diode and corresponding to the red, green and blue pixels. 